Accuracy, Precision, and Significant Figures
Figure 1 A double-pan mechanical balance is used to compare different masses. Usually an object with unknown mass is placed in one pan and objects of known mass are placed in the other pan. When the bar that connects the two pans is horizontal, then the masses in both pans are equal. The “known masses” are typically metal cylinders of standard mass such as 1 gram, 10 grams, and 100 grams. (credit: Serge Melki)
Figure 2 Many mechanical balances, such as double-pan balances, have been replaced by digital scales, which can typically measure the mass of an object more precisely. Whereas a mechanical balance may only read the mass of an object to the nearest tenth of a gram, many digital scales can measure the mass of an object up to the nearest thousandth of a gram. (credit: Karel Jakubec)
By the end of this section, you will be able to:
Science is based on observation and experiment—that is, on measurements. Accuracy is how close a measurement is to the correct value for that measurement. For example, let us say that you are measuring the length of standard computer paper. The packaging in which you purchased the paper states that it is 11.0 inches long. You measure the length of the paper three times and obtain the following measurements: 11.1 in., 11.2 in., and 10.9 in. These measurements are quite accurate because they are very close to the correct value of 11.0 inches. In contrast, if you had obtained a measurement of 12 inches, your measurement would not be very accurate.
The precision of a measurement system is refers to how close the agreement is between repeated measurements (which are repeated under the same conditions). Consider the example of the paper measurements. The precision of the measurements refers to the spread of the measured values. One way to analyze the precision of the measurements would be to determine the range, or difference, between the lowest and the highest measured values. In that case, the lowest value was 10.9 in. and the highest value was 11.2 in. Thus, the measured values deviated from each other by at most 0.3 in. These measurements were relatively precise because they did not vary too much in value. However, if the measured values had been 10.9, 11.1, and 11.9, then the measurements would not be very precise because there would be significant variation from one measurement to another.
The measurements in the paper example are both accurate and precise, but in some cases, measurements are accurate but not precise, or they are precise but not accurate. Let us consider an example of a GPS system that is attempting to locate the position of a restaurant in a city. Think of the restaurant location as existing at the center of a bull's-eye target, and think of each GPS attempt to locate the restaurant as a black dot. In Figure 3, you can see that the GPS measurements are spread out far apart from each other, but they are all relatively close to the actual location of the restaurant at the center of the target. This indicates a low precision, high accuracy measuring system. However, in Figure 4, the GPS measurements are concentrated quite closely to one another, but they are far away from the target location. This indicates a high precision, low accuracy measuring system.
Figure 3 A GPS system attempts to locate a restaurant at the center of the bull's-eye. The black dots represent each attempt to pinpoint the location of the restaurant. The dots are spread out quite far apart from one another, indicating low precision, but they are each rather close to the actual location of the restaurant, indicating high accuracy. (credit: Dark Evil)
Figure 4 In this figure, the dots are concentrated rather closely to one another, indicating high precision, but they are rather far away from the actual location of the restaurant, indicating low accuracy. (credit: Dark Evil)
The degree of accuracy and precision of a measuring system are related to the uncertainty in the measurements. Uncertainty is a quantitative measure of how much your measured values deviate from a standard or expected value. If your measurements are not very accurate or precise, then the uncertainty of your values will be very high. In more general terms, uncertainty can be thought of as a disclaimer for your measured values. For example, if someone asked you to provide the mileage on your car, you might say that it is 45,000 miles, plus or minus 500 miles. The plus or minus amount is the uncertainty in your value. That is, you are indicating that the actual mileage of your car might be as low as 44,500 miles or as high as 45,500 miles, or anywhere in between. All measurements contain some amount of uncertainty. In our example of measuring the length of the paper, we might say that the length of the paper is 11 in., plus or minus 0.2 in. The uncertainty in a measurement, \(A\), is often denoted as \(\delta A\) (“delta \(A\)”), so the measurement result would be recorded as \(A \pm \delta A\). In our paper example, the length of the paper could be expressed as \(11 in.\pm0.2\) .
The factors contributing to uncertainty in a measurement include:
In our example, such factors contributing to the uncertainty could be the following: the smallest division on the ruler is 0.1 in., the person using the ruler has bad eyesight, or one side of the paper is slightly longer than the other. At any rate, the uncertainty in a measurement must be based on a careful consideration of all the factors that might contribute and their possible effects.
Uncertainty is a critical piece of information, both in physics and in many other real-world applications. Imagine you are caring for a sick child. You suspect the child has a fever, so you check his or her temperature with a thermometer. What if the uncertainty of the thermometer were \(3.0^{\circ}C\)? If the child's temperature reading was \(3.0^{\circ}C\) (which is normal body temperature), the “true” temperature could be anywhere from a hypothermic \(34.0^{\circ}C\) to a dangerously high \(40.0^{\circ}C\). A thermometer with an uncertainty of \(3.0^{\circ}C\) would be useless.
___________ indicates the results of the proximity of the measurement with respect to the true value.
Accuracy
Is the proximity between readings made with the same measurement instrument over the same measurand, under specific conditions:
Which represents a more accurate measurement?
Four students are asked to measure the diameter of a commercial compact disc, using the same method and the same instrument. If the real value given by the manufacturer is 12.00 cm. Who has the most precise set of measurements?
Percent Uncertainty
One method of expressing uncertainty is as a percent of the measured value. If a measurement \(A\) is expressed with uncertainty, \(\delta A\), the percent uncertainty (%unc) is defined to be
\(\% unc=\frac {\delta A}{A}\times 100\% \)\(%unc=\frac{\Delta A}{A}\times 100%\)
A grocery store sells \(5\ lb\) bags of apples. You purchase four bags over the course of a month and weigh the apples each time. You obtain the following measurements:
Week 1 weight: \(4.8\ lb\) Week 2 weight: \(5.3\ lb\) Week 3 weight: \(4.9\ lb\) Week 4 weight: \(5.4\ lb\)
You determine that the weight of the \(5\ lb\) bag has an uncertainty of \(\pm0.4\ lb\). What is the percent uncertainty of the bag's weight?
Strategy
First, observe that the expected value of the bag's weight, \(A\), is \(5\ lb\). The uncertainty in this value, \(\delta A\), is \(0.4\ lb\). We can use the following equation to determine the percent uncertainty of the weight:
Solution
Plug the known values into the equation:
Discussion
We can conclude that the weight of the apple bag is \(5\ lb \pm 8\%\). Consider how this percent uncertainty would change if the bag of apples were half as heavy, but the uncertainty in the weight remained the same. Hint for future calculations: when calculating percent uncertainty, always remember that you must multiply the fraction by 100%. If you do not do this, you will have a decimal quantity, not a percent value.
There is an uncertainty in anything calculated from measured quantities. For example, the area of a floor calculated from measurements of its length and width has an uncertainty because the length and width have uncertainties. How big is the uncertainty in something you calculate by multiplication or division? If the measurements going into the calculation have small uncertainties (a few percent or less), then the method of adding percents can be used for multiplication or division. This method says that the percent uncertainty in a quantity calculated by multiplication or division is the sum of the percent uncertainties in the items used to make the calculation. For example, if a floor has a length of \(4.00\;m\) and a width of \(3.00\;m\), with uncertainties of \(2\%\) and \(1\%\), respectively, then the area of the floor is \(12.0\; m^2\) and has an uncertainty of \(3\%\). (Expressed as an area this is \(0.36\;m\), which we round to \(0.4\;m^2\) since the area of the floor is given to a tenth of a square meter.)
An important factor in the accuracy and precision of measurements involves the precision of the measuring tool. In general, a precise measuring tool is one that can measure values in very small increments. For example, a standard ruler can measure length to the nearest millimeter, while a caliper can measure length to the nearest 0.01 millimeter. The caliper is a more precise measuring tool because it can measure extremely small differences in length. The more precise the measuring tool, the more precise and accurate the measurements can be.
When we express measured values, we can only list as many digits as we initially measured with our measuring tool. For example, if you use a standard ruler to measure the length of a stick, you may measure it to be 36.7 \(\mathrm{cm}\). You could not express this value as 36.71 \(\mathrm{cm}\) because your measuring tool was not precise enough to measure a hundredth of a centimeter. It should be noted that the last digit in a measured value has been estimated in some way by the person performing the measurement. For example, the person measuring the length of a stick with a ruler notices that the stick length seems to be somewhere in between 36.6 \(\mathrm{cm}\) and 36.7 \(\mathrm{cm}\), and he or she must estimate the value of the last digit.
Using the method of significant figures, the rule is that the last digit written down in a measurement is the first digit with some uncertainty. In order to determine the number of significant digits in a value, start with the first measured value at the left and count the number of digits through the last digit written on the right. For example, the measured value 36.7 \(\mathrm{cm}\) has three digits, or significant figures. Significant figures indicate the precision of a measuring tool that was used to measure a value.
Special consideration is given to zeros when counting significant figures. The zeros in 0.053 are not significant, because they are only placekeepers that locate the decimal point. There are two significant figures in 0.053. The zeros in 10.053 are not placekeepers but are significant—this number has five significant figures. The zeros in 1300 may or may not be significant depending on the style of writing numbers. They could mean the number is known to the last digit, or they could be placekeepers. So 1300 could have two, three, or four significant figures. (To avoid this ambiguity, write 1300 in scientific notation.) Zeros are significant except when they serve only as placekeepers.
Pound-mass (lbm) is a unit of mass that was used in the UK, where 1 lbm = 0.4539 kg. Suppose you're measuring in lbm with a device with an uncertainty of 2x10-04 kg. What is the percent uncertainty of the device in pound-mass (lbm)?
\(\%unc\;lbm = {\text{uncertainty in kg} \over 0.4539\;kg} \times 100\%\)
\(\%unc\;lbm = {2\times 10^{-04}\;kg \over 0.4539\;kg} \times 100\%\)
Answer: 0.044
Based on the previous percent uncertainty (0.044%), what mass, in pound-mass, has an uncertainty of 1 kg when converted to kilograms?
\(lbm = {\delta\;lbm \over \%unc\;lbm} \times 100\%\)
\(lbm = {1\;kg \over 0.044\%} \times {1\;lbm \over 0.4539\;kg} \times 100\%\)
Answer: 5007.11
A marathon runner completes a 44.855-km course in 2 h, 37 min, and 11 s. There is an uncertainty of 15 m in the distance traveled and uncertainty of 3 s in the elapsed time. Calculate the percent uncertainty in the distance.
\(\%unc\;\text{distance} = {15\;m \over 44.855\;km} \times {1\;km \over 1000\;m} \times 100\% \)
Answer: 0.0334
Calculate the percent uncertainty in the elapsed time.
\(\%unc\;\text{time} = \frac{3\;s}{\text{total time in seconds}} \times 100\%\)
Convert time to seconds:
\(\text {hours to seconds}: 2 \times 3600 = 7200\;s\)
\(\text {minutes to seconds}: 37 \times 60 = 2220\;s\)
\(\%unc\;\text{time} = {3 \over (7200\;s + 2220\;s + 11\;s)} \times 100\%= {3 \over 9431\;s} \times 100\%\)
Answer: 0.0318
What is the average speed in meters per second?
\(\text{average speed} =\frac {44.855 \;km }{(7200\;s + 2220\;s + 11\;s)} \times \frac{1000\;m}{1\;km} = {44855 \over 9431\;s} \times {1000\;m \over 1\;km}\)
\(\text{average speed} = {d \over \text{total time}} \times {1000\;m \over 1\;km}\)
Answer: 4.7561
What is the uncertainty in the average speed?
Express your answer in meters per second.
\(\delta\; \text{speed} = {\%unc\;\text{speed} \over 100\%} \times \text{average speed}({m \over s})\)
\(\%unc\;\text{speed} = \%unc\;\text{distance} + \%unc\;\text{time} = 0.0334\% + 0.0318 \% = 0.0652\%\)
\(\delta\; \text{speed} = {0.0652\% \over 100\%} \times 4.7561\;{m \over s}\)
Answer: 0.0031
A person’s blood pressure is measured to be \(120 \pm 2\;mm\;Hg\). What is its percent uncertainty?
\(\%unc = {2\;mm\;Hg \over 120\;mm\;Hg} \times 100\% = 1.6667\%\)
Answer: 1.6667
Assuming the same percent uncertainty, what is the uncertainty in a blood pressure measurement of 99 mm Hg?
\(\delta\; bp = {1.6667\% \over 100\%} \times 99\;mm\;Hg = 1.65\;mm\;Hg\)
Answer: \( 1.65\)
If the uncertainty is 3, what is the percent uncertainty in 99?
\(\% unc = {3 \over 99} \times 100\;\% = 3.0303\;\%\)
Answer: 3.0303
If the uncertainty is 3, what is the percent uncertainty in 112?
\(\% unc = {3 \over 112} \times 100\;\% = 2.6786\;\%\)
Answer: 2.6786
A good-quality measuring tape can be off by 0.17 cm over a distance of 26 m. What is its percent uncertainty?
\(\% unc\;l = {\delta l \over l} \times 100\;\%\)
\(\% unc\;l = {0.17\;cm \over 26\;m} \times {1\;m \over 100\;cm}\times 100\;\%\)
Answer: 6.54E-3
The length and width of a rectangular room are measured to be \(3.973 \pm 0.002 \;m\) and \(1.078 \pm 0.002 \;m\), respectively.
Calculate the area, in m2, of the room.
\(A = l \times w\)
\(A = 3.973\;m \times 1.078\;m\)
Answer: 4.2829
What is the percent uncertainty in the length?
\(\%unc\;\text{length} = {0.002\;m \over 3.973\;m} \times 100\%\)
Answer: 0.0503
What is the percent uncertainty in the width?
\(\%unc\;\text{width} = {0.002\;m \over 1.078\;m} \times 100\%\)
Answer: 0.1855
Compute the percent uncertainty in the area.
\(\%unc\;\text{area} = \%unc\;\text{length} + \%unc\;\text{width}\)
\(\%unc\;\text{area} = 0.0503\% + 0.1855\%\)
Answer: 0.2359
What is the uncertainty in square meters?
\(\delta\;\text{area} = {\%unc\;\text{area} \over 100\%} \times A \)
\(\delta\;\text{area} = {0.2359\% \over 100\%} \times 4.2829\;m^2 \)
Answer: 0.0101
A car engine moves a piston with a circular cross-section of \(6.048 \pm 0.002 \;cm\) diameter a distance of \(2.684 \pm 0.004 \;cm\) to compress the gas in the cylinder.
By what amount is the gas decreased in volume?
Express your answer in cubic centimeters.
\(V = \pi r^2h\)
\(V = \pi [(0.5)r]^2h\)
\(V = \pi [(0.5)6.048\;cm]^2(2.684\;cm)\)
Answer: 77.1074
What is the percent uncertainty in \(r\)?
\(\%unc\;\text{r} = {0.002\;cm \over 6.048\;cm} \times 100\%\)
Answer: 0.0331
What is the percent uncertainty in \(h\)?
\(\%unc\;\text{h} = {0.004\;cm \over 2.684\;cm} \times 100\%\)
Answer: 0.149
Compute the percent uncertainty in the volume.
\(\%unc\;\text{V} = 2(\%unc\;\text{r}) + \%unc\;\text{h}\)
\(\%unc\;\text{V} = 2(0.0331\%) + 0.149\%\)
Answer: 0.2152
An infant's pulse rate is measured to be 138 + 5 beats/min. What is the percent uncertainty in this measurement?
\(\% unc = {\delta A \over A} \times 100 \%\)
\(\% unc = {5\;beats/min \over 138\;beats/min} \times 100 \% \)
Answer: 3.6232 \(%v{rp}\;{km \over h}\)
A person measures his or her heart rate by counting the number of beats in 30 s . If \(43 \pm 2\) beats are counted in \(30 \pm 1\;s\), what is the heart rate in beats per minute?
\(A = {beats \over minute} = {43\;beats \over 30.0\;s} \times {60\;s \over 1.00\;min}\)
Answer: 86
What is the percent uncertainty?
\(\%unc = \bigg({2\;beat \over 43\;beats} \times 100\% \bigg) + \bigg({1\;s \over 30\;s} \times 100\% \bigg)\)
\(\%unc = 4.6512\% + 3.3333\%\)
Answer: 7.9845
What is the uncertainty in beats per minute?
\(\delta A = {\%unc \over 100\%} \times A\)
\(\delta A = {7.9845\% \over 100\%} \times 86\;{beats \over minute} \)
Answer: 6.8667
Significant Figures in Calculations
When combining measurements with different degrees of accuracy and precision, the number of significant digits in the final answer can be no greater than the number of significant digits in the least precise measured value. There are two different rules, one for multiplication and division and the other for addition and subtraction, as discussed below.
1. For multiplication and division: The result should have the same number of significant figures as the quantity having the least significant figures entering into the calculation. For example, the area of a circle can be calculated from its radius using \(A = \pi r^2 \). Let us see how many significant figures the area has if the radius has only two—say, \(r=1.2\ m\). Then,
is what you would get using a calculator that has an eight-digit output. But because the radius has only two significant figures, it limits the calculated quantity to two significant figures or
even though \(\pi\) is good to at least eight digits.
2. For addition and subtraction: The answer can contain no more decimal places than the least precise measurement. Suppose that you buy 7.56 kg of potatoes in a grocery store as measured with a scale with precision 0.01 kg. Then you drop off 6.052 kg of potatoes at your laboratory as measured by a scale with precision 0.001 kg. Finally, you go home and add 13.7 kg of potatoes as measured by a bathroom scale with precision 0.1 kg. How many kilograms of potatoes do you now have, and how many significant figures are appropriate in the answer? The mass is found by simple addition and subtraction:
Next, we identify the least precise measurement: 13.7 kg. This measurement is expressed to the 0.1 decimal place, so our final answer must also be expressed to the 0.1 decimal place. Thus, the answer is rounded to the tenths place, giving us 15.2 kg.
In this text, most numbers are assumed to have three significant figures. Furthermore, consistent numbers of significant figures are used in all worked examples. You will note that an answer given to three digits is based on input good to at least three digits, for example. If the input has fewer significant figures, the answer will also have fewer significant figures. Care is also taken that the number of significant figures is reasonable for the situation posed. In some topics, particularly in optics, more accurate numbers are needed and more than three significant figures will be used. Finally, if a number is exact, such as the two in the formula for the circumference of a circle, \(C =2 \pi r\), it does not affect the number of significant figures in a calculation.
Which of the following numbers applies the rule "All nonzero digits are significant" to determine its number of significant figures?
Which of the following is a correct way of writing 6, 800 with three significant figures?
A can contains 389 mL of soda. How much is left after 303 mL is removed? Express your answer in milliliters, with the minimum number of significant figures.
\(\text{mL left} = \text{amount of soda - amount removed}\)
\(\text{mL left} = 389\;mL - 303\;mL\)
Which statements are true about sigificant figures?
How many significant figures does the number 1000 have?
Which of the numbers has 4 significant figures?
What is the difference between 100.00 and 100?
Which of the following statements is true about the number of significant figures and the number of decimal places of the numbers 45.6, 4.56, and 0.00456?
Which of the following rules can be applied to determine the number of significant figures in the value of the mass of an object which is 0.005 kg?
When multiplying 350 by 1.75, which of the following must be the final answer?
When dividing 4250 by 20.3, which of the following must be the final answer?
In addition and subtraction of scientific data like measurements, how is the number of significant figures of the final answer determined?
When subtracting 3.2 m from 35.46 m, which of the following must be the final answer?
The radius of a circular table is r = 59 cm. Compute the area of the table in cm2 and express it with the minimum number of significant figures.
\(A=\pi r^2\)
\(A=\pi(59\;cm)^2\)
\(A=10935.884\;cm^2\)
Answer: 10936
A pill has a mass of 8 g, and 121 mg of it is the active sustain. What percentage represents the active sustain? Express the result with two significant figures.
Convert milligrams to grams: \(121({1\;g \over 1000\;mg})=0.121\;g\)
\(0.121({100 \over 8\;g})=1.5125\)%
Answer: 1.5